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Why thermal oil heaters coke upand how to prevent it

Coking is not an oil problem. It is what happens when surface heat flux, flow velocity and film temperature get out of balance — here is how to keep them in line.

  • Flux and velocity must match
  • Film temperature is the limit
  • Prevent at selection AND operation
  • Test carbon residue & acid number

Thermal OilPublished 2026-09-11中文版 ↗

01What coking really is: film temperature exceeding the limit

The layer of oil touching the heater element wall is always hotter than the bulk oil. The higher the wall heat flux and the lower the flow velocity, the bigger that gap becomes. Once the film temperature exceeds the oil's permitted film temperature, the oil cracks and polymerizes: first a dense varnish layer, then carbonized coke.

Coke then feeds itself. Its thermal conductivity is a tiny fraction of steel, so the same power drives wall temperatures even higher and coking accelerates. By the time an operator notices 'same power, lower outlet temperature', the coke layer is often past one millimetre.

02Three root causes, ranked by frequency

Excessive heat flux

Under-sized heating surface to save cost, or a standard circulation heater pushed into high-temperature thermal oil duty. Keep wall flux at or below ~2.5 W/cm² for thermal oil service, lower for high temperatures.

Insufficient velocity

Undersized pump, high system resistance or throttled valves drop the tube-side velocity below 1.5–2 m/s. Slow flow means a thick, hot boundary layer.

Local overheating / dry firing

Pump stopped while heaters stay on, low oil level, or temperature sensors placed where they never see the real wall temperature. Without flow and over-temperature interlocks, coking is only a matter of time.

03Prevention at selection

First, check the flux: total power divided by actual heated surface. Above the oil's permitted value you need larger element diameter, a longer heating section or lower per-element power. Second, confirm the velocity design: the manufacturer should state design flow and pressure drop, and your pump must deliver that velocity inside the heater — not just 'enough head'.

Third, control the ramp-up: cold thermal oil is viscous. Start with one heater group, circulate, de-aerate, then step up. Properly built systems use multi-stage staged energization for exactly this reason.

04Prevention in operation

Heaters off before pump off

Every shutdown sequence must keep circulation running after the heaters de-energize, to carry residual heat out. The trip logic should always cut heating first.

Regular oil analysis

Track carbon residue, acid number and kinematic viscosity. Carbon residue above ~1.5% or acid number above 0.5 mgKOH/g means it is time to replace oil — and hunt for the overheating source.

Watch the expansion tank

Falling expansion tank level and rising vent vapour often indicate internal cracking already underway. Don't write it off as normal losses.

05If coke is already there

Light fouling can be removed with circulating chemical cleaning — then re-verify velocity and temperature rise. If bundles are discoloured or deformed from overheating, replacement is the safer call: the overheated metal has lost its margin, and running it again risks burn-through. Fix the root cause before the new core goes in, or it will repeat the history.

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FAQ

Frequently asked

01What surface heat flux is safe for thermal oil?+

For conventional mineral thermal oil keep wall flux at or below about 2.5 W/cm²; reduce further above 300°C or with synthetic oils. The exact value depends on velocity and the oil's permitted film temperature.

02Can a coked heater be cleaned?+

Light coke responds well to circulating chemical cleaning, followed by verification of velocity and temperature rise. Deformed or heavily overheated bundles should be replaced, and the root cause corrected first.

03How often should thermal oil be tested?+

Typically every 2,000–4,000 running hours or every six months, focusing on carbon residue, acid number and viscosity. Test new systems more frequently until de-aeration is confirmed.

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